An enantiospecific cobaloxime π-cation initiated carbocyclisation

DOI: 10.1016/S0040-4039(98)00163-4

Source and publish data:

Tetrahedron Letters p. 2027 - 2028 (1998)

Update date:2022-08-05

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Authors:

Kettschau, Georg

Pattenden, Gerald

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Article abstract of DOI:10.1016/S0040-4039(98)00163-4

The cationic carbocyclisation of the allyl silane substituted β-hydroxycobaloxime (+)-4 was effected by treatment with catalytic amounts of pTSA to form the cyclopentane derivative (+)-5 which was elaborated to the aldehyde (-) 7 via the alcohol (-)-6. Bo

Full text of DOI:10.1016/S0040-4039(98)00163-4

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