Journal of the American Chemical Society p. 3189 - 3192 (2015)
Update date:2022-08-03
Topics:
Xue, Fei
Zhao, Jin
Hor, T. S. Andy
Hayashi, Tamio
Three-component reaction of aryl Grignard reagents, alkynes, and aryl halides in the presence of 1 mol % of NiCl2 proceeded sequentially through carbomagnesiation of the alkyne followed by cross-coupling of the resulting alkenyl Grignard reagent with aryl halide to give tetrasubstituted alkenes in high yields.
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