Journal of Organic Chemistry p. 900 - 906 (1980)
Update date:2022-08-05
Topics:
Traynor, Sean G.
Kane, Bernard J.
Coleman, Jacquelyn B.
Cardenas, Carlos G.
The utility of the alkoxides of cis- and trans-2-pinanol has been investigated.Yiels comparable to and exceeding those obtained with tert-butoxide are reported for the alkylation of ethyl acetoacetate, for the conversion of α-pinene oxide to trans-pinocarveol and cis-3-pinen-2-ol, and for the isomerization of vinylnorbornene and limonene.Dehydrohalogenation was effected rapidly on bornyl chloride and 2,6-dichlorocamphane-compounds reported to be inert to potassium tert-butoxide in tert-butyl alcohol.Reactions with 1-octyl bromide and with benzyl chloride showed that the pinanoxides have nucleophilicities comparable to that of tert-butoxide.
View MoreChengdu CSH Pharmaceutical Co.,ltd
Contact:+86-(28)-85321971
Address:Block B,New Hope Int. Tian Fu New District, Chengdu, Sichuan, China
Changzhou Jiana Chemical Co.,Ltd
website:http://www.jianachem.com
Contact:86-0519-88731808
Address:Zhenglu Town Wujin City, Jiangsu Province
Tianjin Hedong Red Cliff Chemical Reagent Factory
Contact:+86-022-84780548
Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Jiangxi Global Natural Spice Co., Ltd.
website:https://www.jxhqxl.com/
Contact:+86-796-8106598
Address:No.89, Wenshan Road,South Industrial Park, Jishui County,Jiangxi Province
Xi'an Unique Electronic and Chemical Co., Ltd.
Contact:+86-029-88238008
Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA
Doi:10.1016/S0957-4166(98)00107-4
(1998)Doi:10.1039/c6ob00094k
(2016)Doi:10.1016/S0277-5387(97)00262-3
(1998)Doi:10.1016/j.bmcl.2011.07.117
(2011)Doi:10.1016/S0022-328X(97)00725-0
(1998)Doi:10.1016/S0957-4166(98)00037-8
(1998)
