Enzymes in organic synthesis. 27: Lipase-catalyzed synthesis of (5R,6S)-6-acetoxyalkan-5-olides - Homologues of the mosquito oviposition attractant pheromone

DOI: 10.1002/prac.19973390176

Source and publish data:

Journal fur Praktische Chemie - Chemiker-Zeitung p. 434 - 440 (1997)

Update date:2022-07-31

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Authors:

Henkel Henkel

Kunath Kunath

Schick Schick

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Article abstract of DOI:10.1002/prac.19973390176

Sixteen homologous (5R*,6S*)-6-hydroxyalkan-5-olides rac-5 and their acetoxy derivatives rac-6 were synthesized from the corresponding methyl (Z)-alk-5-enoates 3 by osmium(VIII) oxide catalyzed cis-hydroxylation to the dihydroxy esters rac-4 and hydrolysi

Full text of DOI:10.1002/prac.19973390176

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