Synthesis and structure of binuclear complexes of palladium and platinum containing bridging diphenylphosphinate ligand

DOI: 10.1016/S0277-5387(97)00336-7

Source and publish data:

Polyhedron p. 1317 - 1322 (1998)

Update date:2022-08-02

Topics:

Authors:

Jain, Vimal K.

Butcher, Ray J.

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Article abstract of DOI:10.1016/S0277-5387(97)00336-7

Treatment of [M₂Cl₂(μ-Cl)₂(PR₃)₂] (M/PR₃=Pt/PEt₃, Pt/PBu₃, Pt/PMe₂Ph, Pt/PMePh₂, Pd/PMe₂Ph) with AgO₂PPh₂ at room temperature, gave diphenylphosphinato-bridged binuclear complexes [M₂Q₂(μ-O₂PPh₂) ₂(PR₃)₂]. These complexes were characterized by NMR spectroscopy and elemental analysis. Crystal and molecular structure of [Pt₂Cl₂(μ-O₂PPh₂) ₂(PMe₂Ph)₂] has been determined by single crystal X-ray diffraction. The eight-membered metallocyclic ring Pt₂(O₂P)₂ has a boat conformation with Pt...Pt separation of 3.2212(6) A.

Full text of DOI:10.1016/S0277-5387(97)00336-7

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