
Tetrahedron Letters p. 3795 - 3798 (1998)
Update date:2022-08-05
Topics:
Terauchi, Takeshi
Nakata, Masaya
The C1-C14 portion of altohyrtins (spongistatins) was prepared in a convergent manner from 3,4,6-tri-O-acetyl-D-glucal via a chelation-controlled methylation of ketone, dithiane couplings with epoxides, and a thermodynamically-controlled spitoacetalization.
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