Ligand effects in selective carbonyl addition reactions of organomanganese and cerium reagents

DOI: 10.1016/S0040-4039(00)60907-3

Source and publish data:

Tetrahedron Letters p. 6963 - 6966 (1992)

Update date:2022-08-05

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Authors:

Reetz, Manfred T.

Haning, Helmut

Stanchev, Stephan

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Article abstract of DOI:10.1016/S0040-4039(00)60907-3

Transmetalation of organolithium reagents RLi (R = CH₃, n-Bu) with manganese pivalate produces reagents of the type RMnOC(O)tBu which react stereoselectively with substituted cyclohexanones to afford the axial alcohols preferentially. These rea

Full text of DOI:10.1016/S0040-4039(00)60907-3

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