Intramolecular diels-alder reaction of chiral silatrienes. Synthesis of 4-sila-3,4,4a,5-tetrahydro-2H-isoquinolin-1-one

DOI: 10.1016/S0040-4039(98)00698-4

Source and publish data:

Tetrahedron Letters p. 4261 - 4262 (1998)

Update date:2022-08-02

Topics:

Authors:

Coelho Coelho

Blanco Blanco

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)00698-4

The intramolecular Diels-Alder reaction of a pyran-2-one-6-carboxamide linked to a vinyl dienophile by a chiral silicon atom, followed by CO₂ elimination through a retro Diels-Alder reaction, afforded diastereoselectively a 4-silatetrahydroisoquinolin-2-one.

Full text of DOI:10.1016/S0040-4039(98)00698-4

Products guided by the article

Product name:Isobutyric acid [(benzylamino-methyl)-methyl-vinyl-silanyl]-methyl ester

Cas No:210298-01-4

R&D Labs maybe for 210298-01-4

SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Zhenjiang Haitong Chemical Industry Co., Ltd.

Contact:+86 (511) 8448-0369

Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China
RongCheng K&S Chemical Co.,Ltd

Contact:0631-7336369

Address:rongcheng ,shandong province china
Nanjing Capatue Chemical Co., Ltd

Contact:+86-25-86371192 +86-025-85720158

Address:No.20 Jiangjun Avenue, Jiangning Economic & Technical Development Zone
Anhui Asahikasei Chemical Co., Ltd

Contact:86-551-4259770

Address:No. 88 Linquan Road Hefei Anhui China

Relevant to this article

Doi:10.1021/jo01068a026
(1961)
[{(Fe(PEt₃)₃}₂(μ-H)₆B] [BPh₄]: A complex containing octahedral hypercoordinate boron

Doi:10.1021/ic010477r
(2001)
Doi:10.1016/S0040-4039(00)89511-8
(1968)
The synthesis of 8a-methoxy-2H,6H-chromen-6-ones and corresponding 2H-chromenes by a unique process utilising phenolic oxidation

Doi:10.1016/S0040-4020(97)00008-2
(1997)
New synthetic technology for the synthesis of aryl ethers: Construction of C-O-D and D-O-E ring model systems of vancomycin

Doi:10.1021/ja9636350
(1997)
Total synthesis of vancomycin - Part 1: Design and development of methodology

Doi:10.1002/(SICI)1521-3765(19990903)5:9<2584::AID-CHEM2584>3.0.CO;2-B
(1999)

Article Doi