Intramolecular diels-alder reaction of chiral silatrienes. Synthesis of 4-sila-3,4,4a,5-tetrahydro-2H-isoquinolin-1-one

DOI: 10.1016/S0040-4039(98)00698-4

Source and publish data:

Tetrahedron Letters p. 4261 - 4262 (1998)

Update date:2022-08-02

Topics:

Authors:

Coelho Coelho

Blanco Blanco

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Article abstract of DOI:10.1016/S0040-4039(98)00698-4

The intramolecular Diels-Alder reaction of a pyran-2-one-6-carboxamide linked to a vinyl dienophile by a chiral silicon atom, followed by CO₂ elimination through a retro Diels-Alder reaction, afforded diastereoselectively a 4-silatetrahydroisoquinolin-2-one.

Full text of DOI:10.1016/S0040-4039(98)00698-4

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Product name:Isobutyric acid [(benzylamino-methyl)-methyl-vinyl-silanyl]-methyl ester

Cas No:210298-01-4

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