Tetrahedron Letters p. 4261 - 4262 (1998)
Update date:2022-08-02
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The intramolecular Diels-Alder reaction of a pyran-2-one-6-carboxamide linked to a vinyl dienophile by a chiral silicon atom, followed by CO2 elimination through a retro Diels-Alder reaction, afforded diastereoselectively a 4-silatetrahydroisoquinolin-2-one.
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