Chemiluminescent reactions of ground and metastable states of the group IV a elements with halogens

Article abstract of DOI:10.1063/1.456952

Earlier work on chemiluminescent beam-gas reactions of the ground states (³P_j) of Si, Ge, and Sn with F₂ and of both ground and metastable states (¹D, ¹S) of Sn with Cl ₂, Br₂, and I₂ is extended to include reactions of both ground and metastable states of Si, Ge, and Sn with F₂, Cl₂, Br₂, I₂, and ICl. Chemiluminescent products of metal halides and/or dihalides were observed in all of these reactions, although attempts to observe that in the similar reactions of Pb were unsuccessful. In ICl reactions with Si, Ge, and Sn, both monochloride and dichloride emission occurs, confirming the previously proposed mechanism for creating dihalide emission in Sn reactions with Br₂ and I₂ via a monohalide intermediate.

Full text of DOI:10.1063/1.456952

Chemiluminescent reactions of ground and metastable states of the group IV A
elements with halogens
J. H. Wang, B. S. Cheong, and J. M. Parson
Citation: The Journal of Chemical Physics 91, 2834 (1989); doi: 10.1063/1.456952
View online: http://dx.doi.org/10.1063/1.456952
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/91/5?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.24.51.181 On: Fri, 28 Nov 2014 18:34:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.24.51.181 On: Fri, 28 Nov 2014 18:34:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.24.51.181 On: Fri, 28 Nov 2014 18:34:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.24.51.181 On: Fri, 28 Nov 2014 18:34:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.24.51.181 On: Fri, 28 Nov 2014 18:34:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.24.51.181 On: Fri, 28 Nov 2014 18:34:26