Studies on Transition-metal Nitrido and Oxo Complexes. Part 14. Carboxylato Oxo-osmium(VI) and -ruthenium(VI) Complexes and their Reactions

DOI: 10.1039/DT9920003483

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3483 - 3488 (1992)

Update date:2022-07-29

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Authors:

Griffith, William P.

Jolliffe, Jennifer M.

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Article abstract of DOI:10.1039/DT9920003483

The new complexes (1-) and (1-) (R = Me, Et, Pr or CHF2) have been prepared.In addition to functioning as catalytic oxidants for organic substrates in the presence of N-methylmorpholine N-oxide as co-oxidant, the acetato complexes (1-) in particular can be used as precursors for a wide variety of complexes.New species prepared from these include (2-), (2-), (1-) (acac = pentane-2,4-dionate), (1+) (terpy = 2,2':6',2''-terpyridine), and 1R²)Cl2> (R¹ = R² = Me or Et; R¹ = Me, R² = Et or Ph).

Full text of DOI:10.1039/DT9920003483

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