Studies on Transition-metal Nitrido and Oxo Complexes. Part 14. Carboxylato Oxo-osmium(VI) and -ruthenium(VI) Complexes and their Reactions

DOI: 10.1039/DT9920003483

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3483 - 3488 (1992)

Update date:2022-07-29

Topics:

Authors:

Griffith, William P.

Jolliffe, Jennifer M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9920003483

The new complexes (1-) and (1-) (R = Me, Et, Pr or CHF2) have been prepared.In addition to functioning as catalytic oxidants for organic substrates in the presence of N-methylmorpholine N-oxide as co-oxidant, the acetato complexes (1-) in particular can be used as precursors for a wide variety of complexes.New species prepared from these include (2-), (2-), (1-) (acac = pentane-2,4-dionate), (1+) (terpy = 2,2':6',2''-terpyridine), and 1R²)Cl2> (R¹ = R² = Me or Et; R¹ = Me, R² = Et or Ph).

Full text of DOI:10.1039/DT9920003483

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{Os(dppe)2Cl₂}

Cas No:21199-54-2

R&D Labs maybe for 21199-54-2

Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China
Reliability Assessment Solutions (Changhzou) Co., Ltd.

Contact:86-519-85607515

Address:RM 601-603 BD1 Fuchen Mansion, 8 Taihu East RD, Xinbei District, Changhou, Jiangsu 213022, China
Shijiazhuang Frontierchem Co., Ltd.

Contact:+86-311-89271196

Address:4-4-202 No.15 Biandian Street,Shijiazhuang
WUHAN WELLSONG INT'L CO.,LTD

Contact:+86-27-85733560

Address:NO.308,QINGNIAN RD.,WUHAN,CHINA
Wuxi Innopal International Trade CO.,LTD

Contact:+86-510-80711901-8003

Address:Room 402,Building 5,Longze Garden,No.17,South huanjiu Road,Yixing City, Jiangsu,China

Relevant to this article

The i-motif in the bcl-2 P1 promoter forms an unexpectedly stable structure with a unique 8:5:7 loop folding pattern

Doi:10.1021/ja9076292
(2009)
Doi:10.1139/v69-013
(1969)
Copper-Catalyzed Addition of H-P(O) Bonds to Arynes

Doi:10.1021/acs.joc.6b01776
(2016)
Synthetic studies toward potent cytotoxic agents amphidinolides G and H: Synthesis of the entire C₁₅-C₂₆ moiety of the top half

Doi:10.1016/S0040-4039(98)01699-2
(1998)
Convenient preparation of silylboranes

Doi:10.1021/om000254t
(2000)
Doi:10.1021/jo01264a067
(1969)

Article Doi