Journal of Organic Chemistry p. 9476 - 9482 (2016)
Update date:2022-07-29
Topics:
Chen, Qian
Yan, Xinxing
Wen, Chunxiao
Zeng, Jiekun
Huang, Yulin
Liu, Xingguo
Zhang, Kun
An efficient P-arylation of secondary phosphine oxides has been achieved through the ligand-free copper-catalyzed addition of H-P(O) bonds to in situ generated arynes at room temperature. This transformation provides a straightforward route to the formation of the aryl-P bond with wide functional group compatibility, which produces arylphosphine oxides in up to 99% yield.
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