Tetrahedron p. 3665 - 3674 (1999)
Update date:2022-09-26
Topics: Lipase Chiral center Hydrolysis Catalysis Symmetrical Transformation Alditols Catalyze Mirror image
Gamalevich, Galina D.
Morozov, Boris N.
Vlasyuk, Alexey L.
Serebryakov, Edward P.
L-Fucose and L-xylose were synthesized from dulcitol and xylitol, respectively, using CCL- or PPL-mediated kinetic resolution as the key step. In the first case dissymmetrization was achieved directly by acylating a mesa derivative, while in the second it was preceded by the conversion of the mesa polyol into a racemic intermediate.
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