An external chiral amidophosphine ligand for asymmetric conjugate addition of organocopper

DOI: 10.1016/S0040-4020(98)00485-2

Source and publish data:

Tetrahedron p. 10295 - 10307 (1998)

Update date:2022-09-26

Topics:

Authors:

Nakagawa, Yuichi

Kanai, Motomu

Nagaoka, Yasuo

Tomioka, Kiyoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(98)00485-2

Two types of external, chiral amidophosphine ligands, 1-5, were prepared. Examination of their behavior in an asymmetric conjugate addition reaction of organocuprate revealed the possibility for steric tuning to realize high selectivity.

Full text of DOI:10.1016/S0040-4020(98)00485-2

Products guided by the article

Product name:(S)-(+)-1-aza-3,3-bisbenzyl-8,8-dimethyl-7-oxabicyclo[3.3.0]octan-2-one

Cas No:212890-88-5

R&D Labs maybe for 212890-88-5

Hangzhou Bayee Chemical Co.,Ltd.

Contact:+86-571-86990109

Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
Qingdao Kylin Trading Co., Ltd.

Contact:0086-532-68979884/58972912/68972263/65/88171519

Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
Puyang Huicheng Electronic Material Co., Ltd

website:http://huichengchem.weba.testwebsite.cn/index_en.html

Contact:+86-393-8910800

Address:West Section Shengli Road, Puyang457000, China
ShangHai Ruiyi Medical Technology Co.,Ltd.

Contact:+86-21-54718086

Address:No951 Jianchuan RD，Minhang District
Shandong LuZhou Amino Acid Co., Ltd

Contact:86-539-2218025

Address:yishui economic and technical development zone zhenxing south road

Relevant to this article

Silica-catalysed and highly stereoselective convergent and nonconvergent rearrangements of menthone enol acetate epoxides: Easy access to the four α-hydroxymenthone stereoisomers

Doi:10.1002/ejoc.201200414
(2012)
Stereoselective synthesis of new enantiomerically enriched N-protected θ-camino acetylenic esters

Doi:10.1016/S0040-4020(98)00623-1
(1998)
Novel Disaccharide Chiral Ligands Derived from α,α-Trehalose and Their Applications to Asymmetric Hydrogenation of Enamides

Doi:10.1246/bcsj.71.1967
(1998)
Heck Reaction over Pd-Loaded ETS-10 Molecular Sieve

Doi:10.1246/bcsj.76.1989
(2003)
Investigation of Mn(III)-based oxidative free radical cyclization reactions toward the synthesis of triptolide: The effects of lanthanide triflates and substituents on stereoselectivity

Doi:10.1021/ja993598n
(2000)
Cationic group 4 metal alkyl compounds containing o-arylphenoxide ligation

Doi:10.1021/om980287x
(1998)

Article Doi