An external chiral amidophosphine ligand for asymmetric conjugate addition of organocopper

DOI: 10.1016/S0040-4020(98)00485-2

Source and publish data:

Tetrahedron p. 10295 - 10307 (1998)

Update date:2022-09-26

Topics:

Authors:

Nakagawa, Yuichi

Kanai, Motomu

Nagaoka, Yasuo

Tomioka, Kiyoshi

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Article abstract of DOI:10.1016/S0040-4020(98)00485-2

Two types of external, chiral amidophosphine ligands, 1-5, were prepared. Examination of their behavior in an asymmetric conjugate addition reaction of organocuprate revealed the possibility for steric tuning to realize high selectivity.

Full text of DOI:10.1016/S0040-4020(98)00485-2

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