Tetrahedron Letters p. 6471 - 6474 (1998)
Update date:2022-08-05
Topics:
Kim, Kwan Soo
Park II, Jong
Ding, Pingyu
Oxyselenenylation of cyclopentene with (R,R)-hydrobenzoin and subsequent oxidation-elimination of the resulting oxyselenide 1 afforded olefin 2. Intramolecular oxyselenenylation of 2 occurred in a completely regio- and stereoselective manner to give oxyselenide 3. Further transformation of 2 and 3 provided enatiomerically pure cyclopentanetriol 7, cyclopentanetetrol 9, aminocyclopentitol 15, and cyclopentitol 19.
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Doi:10.1016/S0022-328X(98)00723-2
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(1998)
