An efficient synthesis of cyclophellitol utilizing unusual regioselectivity of oxirane ring opening with Mes2BCH2Li

DOI: 10.1016/S0040-4039(98)01458-0

Source and publish data:

Tetrahedron Letters p. 6939 - 6942 (1998)

Update date:2022-07-31

Topics:

Authors:

Takahashi, Hideyo

Iimori, Takamasa

Ikegami, Shiro

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Article abstract of DOI:10.1016/S0040-4039(98)01458-0

Cyclophellitol has been synthesized from 5,6-enoglucoside efficiently. The carbacyclic skeleton was constructed through a Ferrier reaction mediated by PdCl₂. The regioselectivity on the oxirane ring opening with Mes₂BCH₂Li

Full text of DOI:10.1016/S0040-4039(98)01458-0

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