
Tetrahedron Letters p. 6935 - 6938 (1998)
Update date:2022-08-02
Topics:
Satoh, Tsuyoshi
Yamada, Noriko
Asano, Tohru
Reaction of β-mesyloxy sulfoxides, derived from alkyl (or arylmethyl) phenyl sulfoxides and aldehydes in two steps, with alkylmetal (n-BuLi, t- BuLi, or EtMgBr) at -78°C gave olefins in good to excellent yields. This reaction offers a sulfoxide version of the Julia-Lythgoe olefination.
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