Ligand exchange reaction of sulfoxides in organic synthesis: Sulfoxide version of the Julia-Lythgoe olefination

DOI: 10.1016/S0040-4039(98)01457-9

Source and publish data:

Tetrahedron Letters p. 6935 - 6938 (1998)

Update date:2022-08-02

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Authors:

Satoh, Tsuyoshi

Yamada, Noriko

Asano, Tohru

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Article abstract of DOI:10.1016/S0040-4039(98)01457-9

Reaction of β-mesyloxy sulfoxides, derived from alkyl (or arylmethyl) phenyl sulfoxides and aldehydes in two steps, with alkylmetal (n-BuLi, t- BuLi, or EtMgBr) at -78°C gave olefins in good to excellent yields. This reaction offers a sulfoxide version of the Julia-Lythgoe olefination.

Full text of DOI:10.1016/S0040-4039(98)01457-9

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