Chemistry Letters p. 740 - 741 (2002)
Update date:2022-09-26
Topics:
Ishii, Sei-Ichi
Mitani, Makoto
Saito, Junji
Matsuura, Sadahiko
Kojoh, Shin-Ichi
Kashiwa, Norio
Fujita, Terunori
Zirconium complexes bearing phenoxy/cyclopropyl-, cyclobutyl- or cyclopentyl-imine chelate ligands, when activated with methylalumoxane (MAO), produced vinyl-terminated low molecular weight polyethylenes (Mw < 5000) with higher activities than Cp2ZrCl2 at 25°C. The complex having a cyclobutyl group provided the lowest molecular weight polyethylene (Mw 2100).
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