
Phosphorus, Sulfur and Silicon and the Related Elements p. 193 - 202 (1997)
Update date:2022-08-04
Topics:
Liu, Hua
Xie, Qing-Lan
Li, Songlan
Wang, Ji-Tao
Twenty-five new compounds of the form (PhCH2Me2SiCH2)3SnSP(X)(OR 1)(OR2)(X = O:R1 = C2H5. R2 = Substituted phenyl; X = S:R1 = R2 = hydrocarbyl) have been synthesized. Their structures were characterized by IR, 1H, 119Sn, 31P NMR, MS and elemental analyses. 119Sn NMR measurement of chemical shift have shown that there is a good linear relationship of 119Sn chemical shift with parasubstituent Hammett constants.
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