Novel thiolato-bridged tetranuclear manganese(II) and iron(II) complexes with adamantane-like cores

DOI: 10.1246/cl.1998.971

Source and publish data:

Chemistry Letters p. 971 - 972 (1998)

Update date:2022-09-26

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Authors:

Mikuriya, Masahiro

Kotera, Takanori

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Article abstract of DOI:10.1246/cl.1998.971

Thiolato-bridged tetranuclear manganese(II) and iron(II) complexes, [M₄L^b₃Cl]Cl (M = Mn and Fe; H₂L^b = 2-[bis(2-mercaptoethyl)aminomethyl]pyridine), have been isolated and characterized by X-ray crystallography, which reveals an adamantane-like M₄S₆ core. Magnetic susceptibility data show an overall antiferromagnetic interaction.

Full text of DOI:10.1246/cl.1998.971

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