Tetrahedron Letters p. 8183 - 8186 (1998)
Update date:2022-08-05
Topics:
Alcaraz, Marie-Lyne
Griffin, Frank K.
Paterson, Duncan E.
Taylor, Richard J. K.
Synthetic applications of the title glycals, prepared from S-glycoside dioxides using the Meyers' variant of the Ramberg-Backlund rearrangement are described. These include a formal total synthesis of a novel β-glycosidase inhibitor, and an efficient route to spirocyclic glucose derivatives. In addition, silyl methodology has been developed which allows unprotected exo- glycals to be synthesised.
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Doi:10.1039/a805646c
(1998)Doi:10.1021/om9800187
(1998)Doi:10.1007/BF00481044
()Doi:10.1021/ol0060376
(2000)Doi:10.1021/jo980980u
(1998)Doi:10.1039/CT9252701760
(1925)