Tetrahedron Letters p. 8225 - 8228 (1998)
Update date:2022-08-03
Topics:
Belica, Peter S.
Franck, Richard W.
Easily prepared thioglycosides are oxidized to the sulfone level and then are subjected to Ramberg-Backlund conditions, i.e. a base plus halogenating agent. The products are exo glycals which upon hydrogenation afford C-glycosides.
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Doi:10.1039/b613692c
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