Benzylic C-glycosides via the Ramberg-Backlund reaction

DOI: 10.1016/S0040-4039(98)01881-4

Source and publish data:

Tetrahedron Letters p. 8225 - 8228 (1998)

Update date:2022-08-03

Topics:

Authors:

Belica, Peter S.

Franck, Richard W.

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Article abstract of DOI:10.1016/S0040-4039(98)01881-4

Easily prepared thioglycosides are oxidized to the sulfone level and then are subjected to Ramberg-Backlund conditions, i.e. a base plus halogenating agent. The products are exo glycals which upon hydrogenation afford C-glycosides.

Full text of DOI:10.1016/S0040-4039(98)01881-4

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