Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry p. 801 - 817 (2002)
Update date:2022-08-03
Topics:
Odunola, Olusegun A.
Adeoye, Idowu O.
Woods, Joseph A. O.
The synthesis, spectroscopic, magnetic and biological activities of copper(II) complexes of benzoic acid hydrazides (BAH) and o, m, and p-substituted methylbenzoic acid hydrazides (MBAH) and the single crystal X-ray structure for bis(benzoic acid hydrazide)copper(II) nitrate {Cu[BAH]2(NO3)2} (BAH = Benzoic acid hydrazide) are reported. The composition of the ligands was established by elemental analyses, 1H NMR, and GC-MS. Magnetic susceptibility, electronic and infrared spectral data are consistent with a mononuclear square-planar geometry with bidentate coordination of the hydrazide ligands to give essentially a CuN2O2 chromophore. Cu[BAH]2(NO3)2 crystallizes from methanol solution under ambient temperature in a monoclinic system with a P21/c space system. The copper atom has a nearly regular, four-coordinated, square-planar arrangement with the nitrate anions being uncoordinated in the crystal lattice. The compounds did not show significant activity against selected bacteria and fungi.
puyang hongda shengdao new material co.,ltd.
Contact:+86-393- 4896278
Address:No.29 East Zhongyuan Road
Hubei Xiangxi Chemical Industry Co.,Ltd
Contact:+86-710-3454830
Address:No.7, Daqing East Road, Xiangfan City, Hubei Province, China
Contact:--
Address:80G, No.1 Building, Guodu Development Mansion, No. 182 Zhaohui Road, Hangzhou City, Zhejiang Province,China.
Contact:+86-574- 87178138; 87297407
Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China
Sichuan Mianzhu Ronghong Chemical Co.,LTd
Contact:8613981840544
Address:XINSHI INDUSTRY PARK,MIANZHU,SICHUAN,CHINA
Doi:10.1016/S0022-328X(98)00883-3
(1998)Doi:10.1016/0040-4020(73)80192-9
(1973)Doi:10.1007/BF02290884
(1998)Doi:10.1016/S0040-4020(98)00914-4
(1998)Doi:10.1016/j.ejmech.2021.113624
(2021)Doi:10.1016/S0040-4039(98)02009-7
(1998)
