Tetrahedron Letters p. 5529 - 5532 (1984)
Update date:2022-08-03
Topics:
Tanguy, Guy
Weinberger, Bernd
Abbayes, Hevre des
In a two-phase system (saturated aqueous calcium hydroxide, tetrabutylammonium sulfate, dichloromethane, iron pentacarbonyl) benzyl bromides are readily carbonylated to dibenzyl ketones ; α-α' dibromoorthoxylene yields the o-quinodimethane iron tricarbonyl cmplex 8.It is inferred that the reactions proceed through transient generation of the tetracarbonyl ferrate dianion.
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Doi:10.1021/jo00200a027
(1984)Doi:10.1021/om980701t
(1998)Doi:10.1021/ac00259a034
(1983)Doi:10.1021/jo01093a019
(1959)Doi:10.1021/jo981285p
(1998)Doi:10.1021/ja9820036
(1998)
