Synthesis of benzo[c]phenanthridine alkaloids, using a novel palladium-phosphine combination system - Pd(OAc)2, DPPP, and Bu3P

DOI: 10.1055/s-2002-19799

Source and publish data:

Synthesis p. 237 - 241 (2002)

Update date:2022-09-26

Topics: Synthesis benzo[c]phenanthridine alkaloids Pd(OAc)₂

Authors:

Harayama, Takashi

Akiyama, Toshihiko

Nakano, Yuichiro

Shibaike, Kentaro

Akamatsu, Hisashi

Hori, Akihiro

Abe, Hitoshi

Takeuchi, Yasuo

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Article abstract of DOI:10.1055/s-2002-19799

Total synthesis of several benzo[c]phenanthridine alkaloids was accomplished via an aryl-aryl coupling reaction using a novel Pd reagent prepared from Pd(OAc)₂ DPPP, and Bu₃P. This is a versatile method for the coupling reactions of not only aryl triflates and arenes but also aryl halides and arenes.

Full text of DOI:10.1055/s-2002-19799

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