Efficient syntheses of penta-hydroxylated cyclohexanones via PdCl2- mediated Ferrier-II reaction of 6-O-acetyl-5-enopyranosides

DOI: 10.1016/S0040-4039(98)02231-X

Source and publish data:

Tetrahedron Letters p. 9703 - 9706 (1998)

Update date:2022-08-05

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Authors:

Takahashi, Hideyo

Kittaka, Hisae

Ikegami, Shiro

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Article abstract of DOI:10.1016/S0040-4039(98)02231-X

The conversion of 6-O-acetyl-5-enopyranosides into fully oxygenated cyclohexanones was found to proceed efficiently with a catalytic amount of palladium chloride under neutral conditions. This method was proved to be superior in efficacy to the convention

Full text of DOI:10.1016/S0040-4039(98)02231-X

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