Heterocycles p. 291 - 298 (1999)
Update date:2022-08-05
Topics:
Abe, Hitoshi
Shibaike, Kentaro
Fujii, Hiroyuki
Tsuchida, Daisuke
Akiyama, Teruaki
Harayama, Takashi
The intramolecular Pummerer rearrangement of 2-(2-alkyl-sulfinylphenyl)- 2-propanols (1a, 1c-1g) yielded 1,3-oxathianes (2a, 2c-2g) in the presence of p-toluenesulfonic acid and molecular sieves 3A. Alkyl halides were converted into 1,3-oxathiane derivatives in three steps via this rearrangement.
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(2016)
