Tetrahedron Letters p. 105 - 108 (1999)
Update date:2022-07-31
Topics:
Fukuyama, Yoshiyasu
Yaso, Hideyuki
Nakamura, Kazuhiko
Kodama, Mitsuaki
Plagiochin D (4), a unique macrocyclic bis(bibenzyl) having both a biphenyl ether and a biaryl units isolated from the liverwort Plagiochila acanthophylla, was synthesized. The key 16-membered ring closure of a dibromoperrottetin. A derivative 13 was realized by Pd(0) catalyzed intramolecular Still-Kelly reaction.
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(2019)
