Total synthesis of plagiochin D, a macrocyclic bis(bibenzyl) from liverworts by intramolecular Still-Kelly reaction

DOI: 10.1016/S0040-4039(98)80031-2

Source and publish data:

Tetrahedron Letters p. 105 - 108 (1999)

Update date:2022-07-31

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Authors:

Fukuyama, Yoshiyasu

Yaso, Hideyuki

Nakamura, Kazuhiko

Kodama, Mitsuaki

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Article abstract of DOI:10.1016/S0040-4039(98)80031-2

Plagiochin D (4), a unique macrocyclic bis(bibenzyl) having both a biphenyl ether and a biaryl units isolated from the liverwort Plagiochila acanthophylla, was synthesized. The key 16-membered ring closure of a dibromoperrottetin. A derivative 13 was realized by Pd(0) catalyzed intramolecular Still-Kelly reaction.

Full text of DOI:10.1016/S0040-4039(98)80031-2

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