Enantio- or diastereoselective oxidation of (methylthio)methylphosphonates as a route to precursors of chiral sulfoxides

DOI: 10.1016/S0040-4020(98)01050-3

Source and publish data:

Tetrahedron p. 525 - 532 (1999)

Update date:2022-08-03

Topics:

Authors:

Cardellicchio, Cosimo

Fracchiolla, Giuseppe

Naso, Francesco

Tortorella, Paolo

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Article abstract of DOI:10.1016/S0040-4020(98)01050-3

The enantio- or diastereoselective oxidation of readily available (methylthio)methylphosphonates produces optically active (methylsulfinyl)methylphosphonates which can be used as direct precursors of chiral nonracemic methyl sulfoxides in a substitution reaction involving a carbanionic leaving group.

Full text of DOI:10.1016/S0040-4020(98)01050-3

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Product name:ethyl menthyl (methylthio)methylphosphonate

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