Chemistry of Heterocyclic Compounds p. 1331 - 1336 (1984)
Update date:2022-08-04
Topics:
Gurovets, A. S.
Sharf, V. Z.
Taits, S. Z.
Vol'kenshtein, Yu. B.
Fabrichnyi, B. P.
The dependence of the rate and selectivity of the catalytic hydrodehaligenation of ethyl 2,5-dichloro-3-thienylglyoxylate over immobilized palladium complexes on the nature of the solvent and HCl has been investigated.Hydrogenation of the C=O group also occurs.Reductive dechlorination of methyl and ethyl 2,5-dichloro-3-thienylacetates occurs selectively, at a slower rate than in the case of the 3-thienylglyoxylate.
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