Reactions of 1,4-dioxa-2-silacyclohexanes with acetyl chloride

Article abstract of DOI:10.1007/BF02641552

The reactions of 1,4-dioxa-2-silacyclohexanes with acetyl chloride lead to the cleavage of the Si - O bond to form chlorotriorganosilanes containing the acetoxy group in the organic radical at the silicon atom. Hydrolysis of these chlorosilanes affords bis(acetoxyalkoxy(aryloxy)methyl)disiloxanes, while the reactions with cage copper sodium phenylsiloxane give dodecaphenyl[dodeca(acetoxyorganodimethylsilyloxy)]cyclododecasiloxanes.