Tetrahedron Letters p. 4063 - 4066 (1999)
Update date:2022-08-05
Topics:
Fuentes, Jose
Olano, David
Pradera, M. Angeles
Seven membered iminocyclitols are synthesized in four steps from easily available glycosylenamines (D-gluco, D-galacto, and D-manno configurations) through 1,6-aza-anhydrosugar derivatives. These intermediates are transformed into 2-hydroxy- and 2-unsubstituted azepanes depending on the reactants used for the cleavage of the Cl-O bond. The overall yields are high.
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(1969)
