Tetrahedron p. 6671 - 6680 (1999)
Update date:2022-07-30
Topics:
Srinivasan, Alagar
Pushpan, Simi K.
Ravikumar, Murugaeson
Chandrashekar, Tavarekere K.
Raja, Roy
Synthesis of rubyrins containing two or three heteroatoms (O, S, Se) in the core is accomplished using modified diols and tetrapyrromethanes. Substitution of heteroatoms leads to significant reductions in HOMO-LUMO gap and easier oxidations and reductions reflecting the changes in electronic structure of the rubyrin skeleton.
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