Mixed organofluorine-organosilicon chemistry. 10. Allylation and benzylation of difluoroenoxysilanes. Application to the synthesis of gem- difluoroterpene analogues

DOI: 10.1016/S0040-4020(99)00348-8

Source and publish data:

Tetrahedron p. 7233 - 7242 (1999)

Update date:2022-07-29

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Authors:

Lefebvre, Olivier

Brigaud, Thierry

Portella, Charles

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Article abstract of DOI:10.1016/S0040-4020(99)00348-8

Acylsilane and trifluoromethyltrimethylsilane gave, under fluoride initiation, a difluoroenoxysilane which is used in situ in a Lewis acid catalyzed coupling with a prenyl ester or a benzylic bromide. The advantage of this one-pot procedure was illustrate

Full text of DOI:10.1016/S0040-4020(99)00348-8

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