Synthesis of the enantiopure C15-C26 segment of phorboxazole A and B

DOI: 10.1016/S0040-4039(99)00803-5

Source and publish data:

Tetrahedron Letters p. 4527 - 4530 (1999)

Update date:2022-08-05

Topics:

Authors:

Wolbers, Peter

Misske, Andrea M.

Hoffmann, H. Martin R.

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Article abstract of DOI:10.1016/S0040-4039(99)00803-5

Two approaches towards an enantiopure C15-C26 segment of the phorboxazoles starting from the corresponding C20-C26 aldehyde are presented. A variety of functionalized oxazoles have been synthesized via the rhodium(II) acetate catalyzed cycloaddition of dimethyl diazomalonate to substituted nitriles.

Full text of DOI:10.1016/S0040-4039(99)00803-5

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