
Bulletin of the Chemical Society of Japan p. 1982 - 1987 (1980)
Update date:2022-08-03
Topics:
Takagi, Makoto
Goto, Setsuo
Tazaki, Masato
Matsuda, Tsutomu
The irradiation of organic disulfides in aldehyde solvents resulted in the reductive fission of the S-S linkage, giving an equimolar mixture of the corresponding thiol and thiol acylate in a good yield.The cyclic disulfides gave mono S-acylated dithiols.The reaction proceeded by means of the photo-initiated radical chain mechanism, and AIBN (azobisisobutyronitrile) effected the same reaction under thermal conditions.
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