Tetrahedron Asymmetry p. 613 - 621 (1991)
Update date:2022-08-05
Topics:
Burgess, Kevin
Donk, Wilfred A. van der
Ohlmeyer, Michael J.
Enantioselective hydroborations of alkenes 1 - 4 with catecholborane were performed via catalysis with complexes containing the chiral ligands DIOP, BINAP, CHIRAPHOS, DIPAMP, BDPP, 2-MeODIOP, and 3-MeODIOP.Alkenes 1 - 3 were also hydroborated with catecholborane derivatives 5 - 8 in the presence of Rh(+1)/DIOP catalysts.Trends in the observed optical purities are discussed.
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