Rearrangement Approaches to Cyclic Skeletons. II. Structural Revision and Total Synthesis of (+/-)-Isosesquicarene, a Fused-Ring Sesquiterpene

DOI: 10.1246/bcsj.58.861

Source and publish data:

Bulletin of the Chemical Society of Japan p. 861 - 867 (1985)

Update date:2022-07-30

Topics: Total synthesis Structural revision Sesquiterpene

Authors:

Uyehara, Tadao

Yamada, Jun-ichi

Kato, Tadahiro

Bohlmann, Ferdinand

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Article abstract of DOI:10.1246/bcsj.58.861

The exo-7-(4-methyl-3-pentenyl)derivative of 3-carene(1a), the original structure reported for (+/-)-isosesquicarene, was synthesized starting from tropone, and it was found that 1a is not identical with natural isosesquicarene.The structure of isosesquic

Full text of DOI:10.1246/bcsj.58.861

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