Organic Letters
Letter
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Figure 5. Transformations of oxythiolated products: (A) benzofuran
synthesis; (B) benzothiophene synthesis; (C) further oxythiolation
using a sulfoxide prepared from an oxythiolated product.
ASSOCIATED CONTENT
* Supporting Information
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S
Garg, N. K. J. Am. Chem. Soc. 2016, 138, 10402. (j) Per
́ ́
ez-Gomez, M.;
The Supporting Information is available free of charge on the
García-Lopez, J.-A. Angew. Chem., Int. Ed. 2016, 55, 14389. (k) Li, Y.;
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Muck-Lichtenfeld, C.; Studer, A. Angew. Chem., Int. Ed. 2016, 55, 14435.
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Experimental procedures, characterization for new com-
pounds including NMR spectra (PDF)
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18, 5600. (m) Yoshida, S.; Nakamura, Y.; Uchida, K.; Hazama, Y.;
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AUTHOR INFORMATION
Corresponding Authors
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ORCID
Notes
The authors declare no competing financial interest.
(8) (a) Liu, F.-L.; Chen, J.-R.; Zou, Y.-Q.; Wei, Q.; Xiao, W.-J. Org. Lett.
2014, 16, 3768. (b) Li, H.-Y.; Xing, L.-J.; Lou, M.-M.; Wang, H.; Liu, R.-
H.; Wang, B. Org. Lett. 2015, 17, 1098. (c) Li, Y.; Qiu, D.; Gu, R.; Wang,
J.; Shi, J.; Li, Y. J. Am. Chem. Soc. 2016, 138, 10814.
(9) Li, Y.; Studer, A. Org. Lett. 2017, 19, 666.
(10) Li, X.; Sun, Y.; Huang, X.; Zhang, L.; Kong, L.; Peng, B. Org. Lett.
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Chem. Soc. 2006, 128, 581. (b) Saravanan, P.; Anbarasan, P. Org. Lett.
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ACKNOWLEDGMENTS
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The authors thank Central Glass Co., Ltd. for providing Tf2O.
This work was supported by the Platform Project for Supporting
Drug Discovery and Life Science Research funded by Japan
Agency for Medical Research and Development (AMED); the
Cooperative Research Project of Research Center for Biomedical
Engineering; JSPS KAKENHI Grant Nos. 15H03118 (B; T.H.),
16H01133 (Middle Molecular Strategy; T.H.), 26350971 (C;
S.Y.); 17J08217 (JSPS Research Fellow; K.U.); Naito
Foundation (S.Y.).
(13) (a) Yoshida, S.; Sugimura, Y.; Hazama, Y.; Nishiyama, Y.; Yano,
T.; Shimizu, S.; Hosoya, T. Chem. Commun. 2015, 51, 16613.
(b) Oderinde, M. S.; Frenette, M.; Robbins, D. W.; Aquila, B.;
Johannes, J. W. J. Am. Chem. Soc. 2016, 138, 1760. (c) Kawashima, H.;
Yanagi, T.; Wu, C.-C.; Nogi, K.; Yorimitsu, H. Org. Lett. 2017, 19, 4552.
(d) Kanemoto, K.; Sugimura, Y.; Shimizu, S.; Yoshida, S.; Hosoya, T.
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