Effect of benzylic methyl groups on kinetic basicity of amine ligand in o-boron substituted N,N-dimethylbenzylamines

Article abstract of DOI:10.1246/bcsj.72.1879

Rates of the dissociation of the intramolecular B-N coordination bond in two series of phenylborane derivatives, the boronate and diethylborane complexes, with -CHMeNMe₂ or -CMe₂NMe₂ group at the o-position were determined