Tetrahedron Letters p. 5449 - 5453 (1999)
Update date:2022-07-30
Topics:
Filla, Sandra A.
Song, Jinhua J.
Chen, Lihren
Masamune, Satoru
The C1-C8 and C9-C24 fragments of (-)-discodermolide, the antipode of the marine natural product (+)-discodermolide, have been synthesized with excellent stereoselectivities. These syntheses feature the utilization of the isoxazolidine-mediated asymmetric alkylation methodology and fragment- fragment coupling aldol reactions.
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