Journal of Organometallic Chemistry p. 17 - 29 (1997)
Update date:2022-08-05
Topics:
Lubian, Roman Torres
Paz-Sandoval, M. Angeles
The synthesis, characterization and single-crystal structure determination of chiral compounds (η5-C5R5)Ru(PHPh2)(PPh3)Cl (R=H 3, R=Me 4) and prochiral Cp * Ru(PHPh2)2Cl (6) are described. Compound 6 has been available from reaction of PHPh2 and several starting materials. The X-ray structure comparison between 3, 4 and 6 allowed us to compare the influence of the phosphine, Cp and Cp * ligands in these half-sandwich compounds. In addition, a structural investigation was carried out on Cp * Ru(NBD)Cl (7).
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