Synthesis and thermal decomposition studies of some novel dimethyl(phenyl)silyl-substituted aminoboranes

Article abstract of DOI:10.1080/00945719909351718

Reactions of chloro(dimethyl)phenylsilane with primary amines have been used to obtain a series of compounds having the general formula C₆H₅(CH₃)₂SiNHR. The anions of those species are readily prepared, and may be reacted with trichloroborane or dichlorophenylborane to give the corresponding silylaminoboranes, C₆H₅(CH₃)₂SiN(R)B(X)Cl (X = Cl, Ph). The thermal properties of these silylaminoboranes have been probed using thermogravimetric analysis. The first step in their thermal degradation involves elimination of C₆H₅(CH₃)₂SiCl.

Full text of DOI:10.1080/00945719909351718

Synthesis and Reactivity in Inorganic and Metal-Organic
Chemistry
ISSN: 0094-5714 (Print) 1532-2440 (Online) Journal homepage: http://www.tandfonline.com/loi/lsrt19
Synthesis and Thermal Decomposition Studies
of Some Novel Dimethyl(Phenyl)Silyl-Substituted
Aminoboranes
James R. Bowser , Kristina F. Marohn , Stephanie R. Gilbert & Andrea M.
Robbins
To cite this article: James R. Bowser , Kristina F. Marohn , Stephanie R. Gilbert & Andrea
M. Robbins (1999) Synthesis and Thermal Decomposition Studies of Some Novel
Dimethyl(Phenyl)Silyl-Substituted Aminoboranes, Synthesis and Reactivity in Inorganic and
Metal-Organic Chemistry, 29:9, 1559-1566, DOI: 10.1080/00945719909351718
To link to this article: http://dx.doi.org/10.1080/00945719909351718
Published online: 23 Apr 2008.
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Date: 02 June 2016, At: 01:55