A new and versatile access to azamacroheterocycles via ring closing carbonylative hydroaminomethylation

DOI: 10.1016/S0040-4039(99)01661-5

Source and publish data:

Tetrahedron Letters p. 7773 - 7776 (1999)

Update date:2022-08-03

Topics:

Authors:

Kranemann, Christian L.

Costisella, Burkhard

Eilbracht, Peter

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Article abstract of DOI:10.1016/S0040-4039(99)01661-5

The Rh(I)-catalysed hydroformylation / reductive amination of dienes in the presence of α,ω-diamines is applied to macroheterocyclic ring synthesis. Starting from (hetero)-diallylic systems 12- to 36-membered polyheterocycles are easily accessible.

Full text of DOI:10.1016/S0040-4039(99)01661-5

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