Journal of Carbohydrate Chemistry p. 985 - 997 (1999)
Update date:2022-08-05
Topics:
Nishida, Yoshihiro
Takamori, Yusuke
Matsuda, Kazuhiro
Ohrui, Hiroshi
Yamada, Takeshi
Kobayashi, Kazukiyo
As carbohydrate probes to investigate the biological activity of novel phosphocholine-containing glycoglycerolipids of M. fermentans, artificial glycoconjugate polymers carrying 6-O-phosphocholine α-D-glucopyranoside were synthesized. The synthesis involved α-selective 1-O-p-nitrophenylation (pNP) of 1,6-di-O-acetyl-2,3,4-tri-O-benzyl-D-glucopyranose in the presence of a Lewis acid followed by the introduction of a phosphocholine group at position O-6 by an amidite method. The pNP group was converted into a p-N-methacrylamidophenyl group for subsequent radical polymerization.
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Doi:10.1246/cl.1999.637
(1989)Doi:10.1016/S0040-4020(99)00925-4
(1999)Doi:10.1021/ja9905896
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()Doi:10.1002/(SICI)1521-3773(19991115)38:22<3345::AID-ANIE3345>3.0.CO;2-9
(1999)