Tetrahedron p. 14013 - 14030 (1999)
Update date:2022-08-02
Topics: Diastereoselectivity Experimental terms ester enolate α,β-epoxyaldehydes rationalize
Nacro
Baltas
Gorrichon
Aldol condensations on α,β-epoxyaldehyde having a remote alkoxy group have been realized. A rationalization of the outcome of this condensation is discussed, relying on the dominant conformers revealed by molecular modeling of anti and syn γ,δ-epoxy β-hyd
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