Synthesis and spectroscopic studies on some new pentafluorophenylantimony(III and V) derivatives

Article abstract of DOI:10.1080/00945719909351720

The oxidative addition reaction of (C₆F₅)₂SbCl with ICl and IN₃ yielded (C₆F₅)₂SbI(X)Cl (X = Cl, N₃). (C₆F₅)₂SbN₃ and (C₆F₅)₂SbCl(NCS)N₃ were synthesized by the displacement reactions of (C₆F₅)₂SbCl with NaN₃ in the presence of 15-crown-5 or (C₆F₅)₂SbI(N₃)Cl with AgNCS, respectively. The reaction of bis(pentafluorophenyl)antimony(V) azido derivatives with PhNCS yielded the corresponding 1,2-cycloaddition products i.e., tetrazole-5-thiones The compounds were characterised by elemental analyses, UV, IR and ¹⁹F NMR spectroscopic studies.

Full text of DOI:10.1080/00945719909351720

Synthesis and Reactivity in Inorganic and Metal-Organic
Chemistry
ISSN: 0094-5714 (Print) 1532-2440 (Online) Journal homepage: http://www.tandfonline.com/loi/lsrt19
Synthesis and Spectroscopic Studies on Some New
Pentafluorophenylantimony(Iii and V) Derivatives
A. K. Saxena & Ashok Ranjan
To cite this article: A. K. Saxena & Ashok Ranjan (1999) Synthesis and Spectroscopic Studies
on Some New Pentafluorophenylantimony(Iii and V) Derivatives, Synthesis and Reactivity in
Inorganic and Metal-Organic Chemistry, 29:9, 1579-1591, DOI: 10.1080/00945719909351720
To link to this article: http://dx.doi.org/10.1080/00945719909351720
Published online: 23 Apr 2008.
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Date: 15 June 2016, At: 17:54