Tetrahedron p. 10911 - 10920 (1997)
Update date:2022-08-03
Topics:
Auricchio, Sergio
Bini, Antonella
Pastormerlo, Eros
Truscello, Ada M.
5-Alkoxy-isoxazoles and N,N-disubstituted-5-isoxazolamines were found to isomerize to azirine derivatives by the use of iron dichloride as catalyst. On the contrary 5-alkyl- and 5-aryl-isoxazoles in the presence of the same salt, undergo reductive cleavage to enaminoketones. A common reaction intermediate is proposed.
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