Tetrahedron Letters p. 3565 - 3568 (1999)
Update date:2022-08-04
Topics:
Delouvrie, Benedicte
Lacote, Emmanuel
Fensterbank, Louis
Malacria, Max
The unprecedented radical β-elimination of vinylsulfoxides opens a new access to functionalized di- and trisubstituted allenes. The radical precursors are obtained in two steps from a carbonyl derivative and a vinylsulfoxide. The radical translocation trick can also be used to trigger the β-elimination of the sulfinyl radical.
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