Captodative olefin 3-p-nitrobenzoyloxy-3-buten-2-one as a Diels-Alder ketene equivalent for the synthesis of γ-hydroxycyclohexenones

DOI: 10.1016/S0040-4020(99)00928-X

Source and publish data:

Tetrahedron p. 14535 - 14546 (1999)

Update date:2022-07-30

Topics:

Authors:

Ochoa, Maria E.

Arias, Maria S.

Aguilar, Raul

Delgado, Francisco

Tamariz, Joaquin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(99)00928-X

A short and regioselective synthesis of γ-hydroxycyclohexenones is described, using 3-p-nitrobenzoyloxy-3-buten-2-one (2a) as a ketene equivalent in Diels-Alder reactions with substituted dienes. Oxidation with MCPBA of the α-acetylcyclohexenol derivative

Full text of DOI:10.1016/S0040-4020(99)00928-X

Products guided by the article

Product name:1-acetyl-3,4-dimethyl-3-cyclohexen-1-yl p-nitrobenzoate

Cas No:258266-17-0

R&D Labs maybe for 258266-17-0

Dalian RSD International Trade Co.,Ltd.(expird)

Contact:86-22-60875058 58610575

Address:Wantong International Areas, Hongqiao District, Tianjin, China.China
Jiangsu King Road New Materials Co., Ltd.

website:http://www.jskingroad.com

Contact:0519-85720726 0519-85720721 15006126856

Address:No.1,Weihua Road,Xinbei District,Changzhou City,Jiangsu Province
KA-SHING Business Trade Macau Co., Ltd.

Contact:00853-28430045

Address:23rd Floor, Block 3 La Cite, Areia Preta, Macao
NANCHANG QINZHI SCI&TEC.CO.,LTD(expird)

Contact:+86-13687004106

Address:Hero South Road,Hero Zone,Nanchang,Jiangxi,China
ANHUI CHEM-BRIGHT BIOENGINEERING CO.,LTD

Contact:86-561-4080321

Address:No.8 Lieshan Industrial Zone of Huaibei

Relevant to this article

D-Galactose-derived D-galacturonic acid derivatives suitable as glycosyl acceptors

Doi:10.1016/0008-6215(90)84026-Q
(1990)
Rhodium(I) N-heterocyclic carbene complexes as highly selective catalysts for 1-hexene hydroformylation

Doi:10.1021/om800143m
(2008)
METHYLARSIN- UND METHYLARSINIDEN-METALLCARBONYLE

Doi:10.1016/S0022-328X(00)93946-9
(1981)
Synthesis of new baccatin III derivatives through transesterification of β-keto esters with a protected 10-deacetylbaccatin III

Doi:10.1016/S0040-4039(99)02055-9
(2000)
Secondary amides of (R)-3,3,3-trifluoro-2-hydroxy-2-methylpropionic acid as inhibitors of pyruvate dehydrogenase kinase

Doi:10.1021/jm990358+
(2000)
Antitumour benzothiazoles. Part 32: DNA adducts and double strand breaks correlate with activity; Synthesis of 5F203 hydrogels for local delivery

Doi:10.1016/j.bmc.2015.09.052
(2015)

Article Doi