Application of the β-azidonation reaction to the enantioselective synthesis of the lycorane amaryllidaceae alkaloids

DOI: 10.1016/S0040-4020(99)00850-9

Source and publish data:

Tetrahedron p. 13927 - 13936 (1999)

Update date:2022-08-03

Topics:

Authors:

Magnus Magnus

Bailey Bailey

Porter Porter

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Article abstract of DOI:10.1016/S0040-4020(99)00850-9

The prochiral ketone 5 was treated with the lithium salt of (+)-bis(α- methylbenzyl)amine, followed by triisopropylsilyl trifluoromethanesulfonate to give 10 (96%). β-Azidonation of 10 with (PhlO)(n)/TMSN₃ rapidly produced 11 (95%) as a mixture

Full text of DOI:10.1016/S0040-4020(99)00850-9

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