Application of the β-azidonation reaction to the enantioselective synthesis of the lycorane amaryllidaceae alkaloids

DOI: 10.1016/S0040-4020(99)00850-9

Source and publish data:

Tetrahedron p. 13927 - 13936 (1999)

Update date:2022-08-03

Topics:

Authors:

Magnus Magnus

Bailey Bailey

Porter Porter

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(99)00850-9

The prochiral ketone 5 was treated with the lithium salt of (+)-bis(α- methylbenzyl)amine, followed by triisopropylsilyl trifluoromethanesulfonate to give 10 (96%). β-Azidonation of 10 with (PhlO)(n)/TMSN₃ rapidly produced 11 (95%) as a mixture

Full text of DOI:10.1016/S0040-4020(99)00850-9

Products guided by the article

Product name:(3R,4R)-4-(1,3-benzodioxol-5-yl)-N-(2-bromoethyl)-3-(4-toluenesulfonamido)-1-triisopropylsilyl(oxy)cyclohexene

Cas No:258521-72-1

R&D Labs maybe for 258521-72-1

Zhejiang Chemicals Import & Export Corporation

Contact:86-571-87043088

Address:No.37,Qingchun Road,Hangzhou,China
Beyond Pharmaceutical Co., Ltd

Contact:+86-571-8195-3185

Address:No. 13-1, Liansheng Road, Yuhang District
Shanghai Hohance Chemical Co., ltd

Contact:13914753421

Address:Fl.5；Bld. 70, Lane 1500; Xinfei Road
Hangzhou Maytime Bio-Tech Co.,Ltd.

website:http://www.maytime.com.cn

Contact:+86-571-88925295 88920965

Address:NO.2-1701 Ganghui Central Ningwei Street, Xiaoshan Hangzhou Zhejiang China
Shanghai Longjin Metallic Material Co., Ltd.

website:http://www.shlongjin.cn/

Contact:021-56517503,56502257

Address:No.16, Lane 555, Chengyin Road, Shanghai

Relevant to this article

Aryl H-phosphonates. Part 11. Synthetic and ³¹P NMR studies on the formation of aryl nucleoside H-phosphonates

Doi:10.1039/a907150d
(1999)
Chiral 4-(diphenylphosphanyl)-1-(dialkylamino)butane ligands - Synthesis, applications in asymmetric alkylation and theoretical study

Doi:10.1002/(SICI)1099-0682(200002)2000:2<351::AID-EJIC351>3.0.CO;2-Q
(2000)
Trimethylsilyltriflate-promoted addition of 2-trimethylsilyloxyfuran to a chiral cyclic nitrone; a short synthesis of [1S(1α,2β,7β,8α,8aα)]-1,2- di(t-butyldiphenylsilyloxy)-indolizidine-7,8-diol

Doi:10.1016/S0040-4020(99)01001-7
(2000)
Sulfite-Induced N-Alkylation and Thioketonization of Azoles Enable Access to Diverse Azole Thiones

Doi:10.1002/adsc.201801166
(2018)
Investigation of the aqueous transmetalation of π-allylpalladium with indium salt: The use of the Pd(OAc)₂-TPPTS catalyst

Doi:10.1039/b419231c
(2005)
Synthesis of novel chiral crown ethers derived from D-glucose and their application to an enantioselective Michael reaction

Doi:10.1039/a905670j
(1999)

Article Doi